docs: document PODCAST_ONLY_DEMO_MODE deployment toggle and release check

[AJaySi]

Motivation

• Add explicit deployment guidance for a temporary podcast demo toggle so testers can enable PODCAST_ONLY_DEMO_MODE during demoing and ensure it is cleared before production, while leaving all feature code paths intact.

Description

• Updated docs-site/docs/user-journeys/developers/deployment.md to document the PODCAST_ONLY_DEMO_MODE environment variable and example values.
• Added inline guidance showing PODCAST_ONLY_DEMO_MODE=true enables demo-only behavior and that PODCAST_ONLY_DEMO_MODE=false (or leaving it unset) restores full behavior.
• Added a Release Checklist (Demo-Mode Safety) section with a checklist item to confirm the demo flag is unset or explicitly false before finalizing a release.

Testing

• Verified the documentation change by inspecting the updated file content with nl -ba and targeted sed/rg searches, which showed the new PODCAST_ONLY_DEMO_MODE lines and checklist entry were present and correct.
• No unit or integration tests were required because this is a documentation-only change.

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Codex Task