FindLibOVR detects the SDK version to be used by using CMAKE_GENERATOR_PLATFORM https://github.com/robotology/ycm/blob/32e544488537e435d61ffe237bb72f3908552c9c/find-modules/FindLibOVR.cmake#L55
On Visual Studio 16 2019 this variable is not set, thus defaulting to the 32bit version.
@traversaro