I'm not sure whether it's possible to trigger bibliography completion list in-situ in TeX source document when typing \cite{} command. I noticed some related discussion here:
The documentation of reftex-citation is a bit confusing. It promises completion on known citation keys but I believe "known" refers to keys that have been used previously in this session rather than all keys in the appropriate bibliography. You can use the LaTeX-add-all-bibitems-from-bibtex command defined below to load all keys in your bibliography:
(defun get-bibtex-keys (file)
(with-current-buffer (find-file-noselect file)
(mapcar 'car (bibtex-parse-keys))))
(defun LaTeX-add-all-bibitems-from-bibtex ()
(interactive)
(mapc 'LaTeX-add-bibitems
(apply 'append
(mapcar 'get-bibtex-keys (reftex-get-bibfile-list)))))
Suggestions on appropriate hooks to make this happen automatically are welcome.
But I'm not sure whether helm-bibtex supports a similar feature.
Regards,
Zhao